Lipase-catalyzed enantio- and regioselective transformation of 3-epi-shikimic acid derivatives as the key step for the entry of polyoxygenated carbacycles

DOI: 10.1016/j.molcatb.2010.07.009

Source and publish data:

Journal of Molecular Catalysis B: Enzymatic p. 78 - 84 (2010)

Update date:2022-09-26

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Authors:

Hamada, Manabu

Higashi, Toshinori

Shoji, Mitsuru

Umezawa, Kazuo

Sugai, Takeshi

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Article abstract of DOI:10.1016/j.molcatb.2010.07.009

Candida antarctica lipase B (Novozym 435)-catalyzed transesterification on methyl (±)-3,4-di-O-acetyl-5-O-(tert-butyldimethyl)silyl-3-epi-shikimate worked highly regio- and enantioselective manner. Only (3R,4S,5S)-isomer reacted with an E value over 500,

Full text of DOI:10.1016/j.molcatb.2010.07.009

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