Asymmetric Synthesis of (1-Aminoalkyl)phosphonic Acids via Asymmetric Aldol Reaction of (Isocyanomethyl)phosphonates Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex

DOI: 10.1016/S0040-4039(00)99660-6

Source and publish data:

Tetrahedron Letters p. 2247 - 2250 (1989)

Update date:2022-08-04

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Authors:

Sawamura, Masaya

Ito, Yoshihiko

Hayashi, Tamio

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Article abstract of DOI:10.1016/S0040-4039(00)99660-6

Reaction of aldehydes (R¹CHO: R¹ = Ph, i-Pr, 3,4-OCH2O-C6H3) with (isocyanomethyl)phosphonates (CNCH2P(O)(OR²)2: R² = Et, Ph) in the presence of 1 molpercent of a chiral ferrocenylphosphine-gold(I) catalyst gave

Full text of DOI:10.1016/S0040-4039(00)99660-6

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Product name:((1R,2R)-1-Amino-2-hydroxy-2-phenyl-ethyl)-phosphonic acid diethyl ester; hydrochloride

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