Chemical and Pharmaceutical Bulletin p. 429 - 438 (2014)
Update date:2022-08-02
Topics:
Fujisaki, Fumiko
Aki, Hatsumi
Naito, Ayumi
Fukami, Enko
Kashige, Nobuhiro
Miake, Fumio
Sumoto, Kunihiro
In connection with our studies on hydantoin derivatives, a conventional regioselective chemical transformation of 5-methylene hydantoins 4a-c to 5-aminomethyl-substituted hydantoins 5-10 or to 5-amino-5-methyl-disubstituted hydantoins 11-14 is described. Synthesis of bivalent twin-drug type hydantoin derivatives 19-24 and the binding property of a bivalent symmetrical hydantoin derivative 24b to sulfated glycosaminoglycans are also described.
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Doi:10.1021/ja982488y
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