Tandem cyclization-cycloaddition reaction of rhodium carbenoids. Scope and mechanistic details of the process

DOI: 10.1021/ja00164a034

Source and publish data:

Journal of the American Chemical Society p. 3100 - 3109 (1990)

Update date:2022-07-29

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Authors:

Padwa Padwa

Fryxell Fryxell

Zhi Zhi

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Article abstract of DOI:10.1021/ja00164a034

Treatment of 1-diazo-2,5-pentanediones with rhodium(II) carboxylates affords cyclic six-ring carbonyl ylide dipoles. These species undergo facile 1,3-dipolar cycloaddition with both electron-deficient and electron-rich dipolarophiles. In certain cases 2:1

Full text of DOI:10.1021/ja00164a034

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