Synthesis p. 661 - 666 (1989)
Update date:2022-08-04
Topics:
Fouque, Elie
Rousseau, Gerard
The horse liver and pig liver esterase hydrolysis of racemic medium ring lactones gives with excellent enantiomeric excess the S- (or R) lactones and the corresponding R- (or S) hydroxy acids.This is the first general method to obtain optically pure medium ring lactones.Application to the preparation of (S)-(+)-Phoracantholide I is reported.
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(1957)
