Enantioselective C-C Bond Formation during the Oxidation of 5-Phenylpent-2-enyl Carboxylates with Hypervalent Iodine(III)

DOI: 10.1021/acs.joc.7b01141

Source and publish data:

Journal of Organic Chemistry p. 11836 - 11840 (2017)

Update date:2022-08-05

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Authors:

Shimogaki, Mio

Fujita, Morifumi

Sugimura, Takashi

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Article abstract of DOI:10.1021/acs.joc.7b01141

The oxidation of (5-acyloxypent-3-enyl)benzene with hypervalent iodine(III) afforded 2-oxy-1-(oxymethyl)tetrahydronaphthalene under metal-free conditions. The acyloxy group may nucleophilically participate in the oxidative cyclization. A lactate-based chi

Full text of DOI:10.1021/acs.joc.7b01141

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