Synthesis p. 688 - 690 (1989)
Update date:2022-08-05
Topics:
Choudhary, Anil
Baumstark, Alfons L.
A general method for the facile dimethylation of 1,3-diketones is presented.The method involves the use of readily available, inexpensive reagents and is carried out under mild conditions.Monomethylation may be carried out by slight modification (simplification) of the procedure.Several examples are presented which show that the method is applicable to alkylations with primary halides as well.Isolated yields for monoalkylation are approximately 95percent while those for dialkylation are ca. 90percent.Alkylation is taking place by the reaction of the enolates of 1,3-diketones
Zhejiang Quzhou Jiancheng Silicone Co., Ltd.(Shanghai Jiancheng Industial and Trade Co, Ltd)
Contact:18957018777 +86-570-3888777
Address:The company production base address： Quzhou City, Zhejiang Province high-tech industrial park Nianhua Road 37
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd
Contact:86-0312-6615158
Address:No 42 fazhan street qingyuan county
Shifang Taifeng New Flame Retardant Co., Ltd
Contact:02884721008
Address:tingjiang industrial park, hefeng town
ZiBO KuoDing Trade company Ltd
website:http://www.sdzbkd.com
Contact:86-13361591822
Address:GongQingTuan road
Shenyang Xingzhenghe Chemical Co., Ltd.
Contact:024-23509232
Address:No. 33, Naner Road, Heping Dist.
Doi:10.1016/j.bmcl.2010.10.141
(2011)Doi:10.1021/jo102263t
(2011)Doi:10.1007/s00044-010-9507-y
(2012)Doi:10.1016/j.tetlet.2010.11.080
(2011)Doi:10.1002/aoc.1720
(2011)Doi:10.1016/j.tetasy.2011.04.019
(2011)
