Tetrahedron Letters p. 3805 - 3806 (1989)
Update date:2022-08-02
Topics:
Takano, Seiichi
Moriya, Minoru
Iwabuchi, Yoshiharu
Ogasawara, Kunio
Treatment of (S)-1-benzyloxy-2-benzoylaminohex-5-ene with iodine in aqueous acetonitrile furnished (2S,5S)-5-benzoyloxymethyl-2-bemzyloxymethylpyrrolidine stereoselectively in a single step.The product was converted into C2-symmetric (2S,5S)-2,5-dioxymethylpyrrolidines potentially utilizable as chiral auxiliaries and (2S,5S)-(-)-pyrrolidine-2,5-dicarboxylic acid isolated from marine alga Schizymenia dubyi.
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