Organosilver complexes. Synthesis and crystal structure of the ylide disilver complex [AgCH2P(S)Ph2]2

Article abstract of DOI:10.1021/om00156a045

A dimeric silver(I) complex, [Ag(CH₂PPh₂S)]₂ (1), was obtained by the reaction of Li(CH₂PPh₂S) with AgNO₃ in THF solution at -78°C. The X-ray crystal structure of 1 shows that the ylide lig