Silver(I)-catalyzed asymmetric aldol reaction of isocyanoacetate

DOI: 10.1016/0040-4039(91)85090-R

Source and publish data:

Tetrahedron Letters p. 2799 - 2802 (1991)

Update date:2022-08-03

Topics:

Authors:

Hayashi, Tamio

Uozumi, Yasuhiro

Yamazaki, Akiko

Sawamura, Masaya

Hamashima, Hitoshi

Ito, Yoshihiko

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Article abstract of DOI:10.1016/0040-4039(91)85090-R

High stereoselectivity (over 80% ee) was attained in silver(I)-catalyzed asymmetric aldol reaction of methyl isocyanoacetate with aldehydes in the presence of a chiral (aminoalkyl)ferrocenylphosphine-silver(I) complex by slow addition of the isocyanoaceta

Full text of DOI:10.1016/0040-4039(91)85090-R

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