A Novel Reaction of CS2 with Organocopper(I) Complexes. Synthesis and Structure of di-μ4-trithiocarbonato>tetracopper(I)-Toluene

DOI: 10.1039/c39830001126

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1126 - 1128 (1983)

Update date:2022-09-26

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Authors:

Lanfredi, Anna Maria Manotti

Tiripicchio, Antonio

Camus, Annamaria

Marsich, Nazario

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Article abstract of DOI:10.1039/c39830001126

The reaction of some arylcopper(I) complexes with carbon disulphide and bis(diphenylphosphino)methane (dppm), in toluene, affords the trithiocarbonato complex , whose structure, as the toluene solvate, was shown by X-ray analysis to consist of a square arrangement of copper atoms with the dppm ligands bridging the edges; each of the two trithiocarbonate anions is bonded to all the four copper atoms through two sulphur atoms only.

Full text of DOI:10.1039/c39830001126

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