A Novel Reaction of CS2 with Organocopper(I) Complexes. Synthesis and Structure of di-μ4-trithiocarbonato>tetracopper(I)-Toluene

DOI: 10.1039/c39830001126

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1126 - 1128 (1983)

Update date:2022-09-26

Topics:

Authors:

Lanfredi, Anna Maria Manotti

Tiripicchio, Antonio

Camus, Annamaria

Marsich, Nazario

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830001126

The reaction of some arylcopper(I) complexes with carbon disulphide and bis(diphenylphosphino)methane (dppm), in toluene, affords the trithiocarbonato complex , whose structure, as the toluene solvate, was shown by X-ray analysis to consist of a square arrangement of copper atoms with the dppm ligands bridging the edges; each of the two trithiocarbonate anions is bonded to all the four copper atoms through two sulphur atoms only.

Full text of DOI:10.1039/c39830001126

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Cu⁽¹⁺⁾*Cl^(1-)*(C₆H₅)2PCH₂P(C₆H₅)2=CuCl((C₆H₅)2PCH₂P(C₆H₅)2)

Cas No:12689-16-6

R&D Labs maybe for 12689-16-6

Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province
Quzhou Ruiyuan chemical Co., Ltd

Contact:+86-570-3039321/3039361/3039308

Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.
SHIJIAZHUANG AGERUO-BIOTECH CO.LTD

Contact:+86-130-2866-6699

Address:Huaian east Road 158
Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China
BOC Sciences

website:https://www.bocsci.com/

Contact:1-631-485-4226

Address:Ramsey Road

Relevant to this article

Synthesis of 5-arylmethylene-1,3-dioxolan-4-ones and β-aryl-α-ketocarboxylic acids

Doi:10.1055/s-1989-27439
(1989)
Interaction of 1,3,2,4-benzodithiadiazines and their 1-Se congeners with Ph₃P and some properties of the iminophosphorane products

Doi:10.1021/ic102565x
(2011)
Fine-tuning the selectivity of aldosterone synthase inhibitors: Structure-activity and structure-selectivity insights from studies of heteroaryl substituted 1,2,5,6-tetrahydropyrrolo[3,2,1- ij ]quinolin-4-one derivatives

Doi:10.1021/jm101470k
(2011)
Stereoselective synthesis of 1,1-dialkyl-1-methoxymethyl glucosides (acetal-glucosides).

Doi:10.1016/0008-6215(89)85015-3
(1989)
Novel Synthesis of syn-α,β-Epoxy Alcohols by Diastereoselective Carbonyl Reduction of α,β-Epoxy Ketones

Doi:10.1016/S0040-4039(00)78454-1
(1994)
Regioselectivity of nucleophilic additions to substituted (η⁴-diene)Co(CO)3BF4 complexes

Doi:10.1016/0022-328X(90)87128-Z
(1990)

Article Doi