TOTAL SYNTHESIS OF (+)-SPATOL. A STEREOSPECIFIC CONSTRUCTION OF VICINAL DIEPOXIDES FROM 2,3-EPOXY-1,4-DIOLS

DOI: 10.1016/S0040-4039(01)80758-9

Source and publish data:

Tetrahedron Letters p. 4621 - 4625 (1989)

Update date:2022-08-05

Topics:

Authors:

Salomon, Robert G.

Basu, Basudeb

Roy, Subhas

Sharma, Ram B.

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Article abstract of DOI:10.1016/S0040-4039(01)80758-9

A total synthesis of (+)-spatol (1) was achived which depends upon a novel stereospecific transformation of trans-2,3-epoxy-1,4-diols to generate sensitive allylic vicinal cis-epoxide in 1.

Full text of DOI:10.1016/S0040-4039(01)80758-9

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