PHOTOCYCLOADDITION REACTIONS OF TRICYCLO2,8>NONA-3,6-DIEN-9-ONE (BARBARALONE) AND CARBONYL COMPOUNDS

DOI: 10.1016/S0040-4039(01)93769-4

Source and publish data:

Tetrahedron Letters p. 5297 - 5300 (1989)

Update date:2022-08-04

Topics:

Authors:

Miyashi, Tsutomo

Konno, Akinori

Takahashi, Yatsutake

Kaneko, Atsuko

Suzuki, Takanori

at al. at al.

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Article abstract of DOI:10.1016/S0040-4039(01)93769-4

Barbaralone undergoes two types of cycloadditions with photoexcited p-chloranil, p-bromanil, and p-fluoranil at the C1-C3 and C4-C6 positions possibly through a locally excited triplet exciplex and an ion radical pair, respectively.

Full text of DOI:10.1016/S0040-4039(01)93769-4

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Product name:4-Hydroxy-8-(2,3,5,6-tetrachloro-4-hydroxy-phenoxy)-bicyclo[3.3.1]nona-2,6-dien-9-one

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