Experimental Evidence for the Lack of Stereoselectivity in the Electrophilic Quench of α-Sulfonyl Carbanions

DOI: 10.1021/jo00299a028

Source and publish data:

Journal of Organic Chemistry p. 3840 - 3846 (1990)

Update date:2022-09-26

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Authors:

Williams, Richard Vaughan

Kelley, Geoffrey W.

Loebel, Jorg

Helm, Dick van der

Page, Philip C. Bulman

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Article abstract of DOI:10.1021/jo00299a028

A series of α-sulfonyl carbanions was generated from the corresponding bridged bicyclic sulfones.These anions were quenched with a variety of electrophiles, and the stereoselectivity of these reactions were examined.Stereochemical assignments were based o

Full text of DOI:10.1021/jo00299a028

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