Experimental Evidence for the Lack of Stereoselectivity in the Electrophilic Quench of α-Sulfonyl Carbanions

DOI: 10.1021/jo00299a028

Source and publish data:

Journal of Organic Chemistry p. 3840 - 3846 (1990)

Update date:2022-09-26

Topics:

Authors:

Williams, Richard Vaughan

Kelley, Geoffrey W.

Loebel, Jorg

Helm, Dick van der

Page, Philip C. Bulman

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00299a028

A series of α-sulfonyl carbanions was generated from the corresponding bridged bicyclic sulfones.These anions were quenched with a variety of electrophiles, and the stereoselectivity of these reactions were examined.Stereochemical assignments were based o

Full text of DOI:10.1021/jo00299a028

Products guided by the article

Product name:5-endo-(Phenylsulfonyl)-5-exo-(trimethylsilyl)bicyclo<2.2.2>oct-2-ene

Cas No:127311-33-5

R&D Labs maybe for 127311-33-5

Nanjing distinctions Medical Technology Co., Ltd.(expird)

Contact:+86-15996203785 13914714059

Address:nanjing,jiangsu , China
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Synasia Inc

Contact:17316303296

Address:240 Amboy Ave
Lanzhou huibang biological chemical technology Co., LTD

Contact:0931-7843964

Address:NO.2011,Yannan Road,Chengguan,
Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan

Relevant to this article

Facile and efficient one-pot synthesis of 4β-arylamino-podophyllotoxins: Synthesis of DNA topoisomerase II inhibitors (NPF and W-68)

Doi:10.1016/S0960-894X(00)00407-8
(2000)
A traceless directing group for C - H borylation

Doi:10.1002/anie.201306511
(2013)
Total synthesis of (+)-aspergillide C

Doi:10.1016/j.tetlet.2011.01.078
(2011)
Vicarious nucleophilic substitution of hydrogen in nitroderivatives of five-membered heteroaromatic compounds

Doi:10.1016/0040-4020(95)00445-E
(1995)
Synthese neuer 1,3-Oxazinone aus Cyanamiden und Chlorocarbonylketenen

Doi:10.1055/s-1990-26823
(1990)
Ultrasonic-based protein quantitation by¹⁸O-labeling: Optimization and comparison between different procedures

Doi:10.1002/rcm.4816
(2011)

Article Doi