ALLENE SYNTHESIS FROM 2-ALKYN-1-OLS

DOI: 10.1016/S0040-4039(00)76187-9

Source and publish data:

Tetrahedron Letters p. 5747 - 5750 (1989)

Update date:2022-07-31

Topics:

Authors:

Myers, Andrew G.

Finney, Nathaniel S.

Kuo, Elaine Y.

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Article abstract of DOI:10.1016/S0040-4039(00)76187-9

Activation of 2-alkyn-1-ols as their methanesulfonate esters and displacement with hydrazine furnishes the corresponding alkynyl hydrazine derivatives which undergo smooth oxidative rearrangement with diethyl azodicarboxylate (DEAD) or 4-methyl-1,2,4-tria

Full text of DOI:10.1016/S0040-4039(00)76187-9

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