Diels-Alder reaction of chiral dienes. Remarkable effect of dienophile polarity upon diastereo face selectivity

DOI: 10.1016/S0040-4039(01)93907-3

Source and publish data:

Tetrahedron Letters p. 6405 - 6408 (1989)

Update date:2022-08-05

Topics:

Authors:

Hamada Hamada

Sato Sato

Hikota Hikota

Yonemitsu

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Article abstract of DOI:10.1016/S0040-4039(01)93907-3

Face selectivity of Diels-Alder reaction of diene having the stereogenic center at allylic position depends on dienophile polarity, and hetero Diels-Alder reaction with dienophile such as N-tosylimine and N-tosylsulfinylimine was found to give exclusively

Full text of DOI:10.1016/S0040-4039(01)93907-3

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