Tetrahedron Letters p. 3811 - 3814 (1991)
Update date:2022-08-05
Topics:
Barton, Derek H. R.
Doller, Dario
Geletii, Yurii V.
Kinetic isotopic effects (KIE) were measured for oxidation, bromination and selenylation of c-C6H12/c-C6D12 in pyridine solution for different Gif-type, Fenton and other systems.The comparison of KIE and relative reactivity data for the pair c-C5H10/c-C6H12 proved that the mechanism of activation in Gif-type reactions is different from a hydrogen atom abstraction.
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