HIGHLY STEREOSELECTIVE RADICAL ADDITION TO A TRISUBSTITUTED ALKENE BY LOW TEMPERATURE PHOTOLYSIS OF THIOHYDROXAMIC ESTERS

DOI: 10.1016/S0040-4039(00)88852-8

Source and publish data:

Tetrahedron Letters p. 1679 - 1682 (1990)

Update date:2022-07-29

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Authors:

Scott, Daniel M.

McPhail, Andrew T.

Porter, Ned A.

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Article abstract of DOI:10.1016/S0040-4039(00)88852-8

Low temperature carbon radical addition to α,β-unsaturated amides of trans-2,5-dimethylpyrrolidine was achieved in high yield with high diastereoselectivity by photolysis of Barton esters.Use of an olefin substituted with three electron withdrawing groups

Full text of DOI:10.1016/S0040-4039(00)88852-8

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