Journal of the Chemical Society. Chemical communications p. 448 - 449 (1990)
Update date:2022-07-29
Topics:
Haynes, Richard K.
Vonwiller, Simone C.
Whereas primary and secondary allylic hydroperoxides are quantitatively converted by tributyltin methoxide into stannyl peroxides, whose treatment with trityl chloride, chloromethyl methyl ether, and t-butyldimethylsilyl trifluoromethane-sulphonate give the corresponding trityl, methoxymethyl, and silyl peroxides, a tertiary allylic hydroperoxide gives rearrangement products on stannylation and treatment with trityl chloride.
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