SYNTHESIS OF AN ADVANCED QUINOCARCIN INTERMEDIATE FROM L-GLUTAMIC ACID

DOI: 10.1016/0040-4039(90)80083-X

Source and publish data:

Tetrahedron Letters p. 2105 - 2108 (1990)

Update date:2022-08-05

Topics:

Authors:

Lessen, Thomas A.

Demko, Donald M.

Weinreb, Steven M.

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Article abstract of DOI:10.1016/0040-4039(90)80083-X

A key intramolecular N-acyliminium ion/silylenol ether cyclization of 17, derived from L-glutamic acid, has been used to construct the bridged bicyclic quinocarcin intermediate 3.

Full text of DOI:10.1016/0040-4039(90)80083-X

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