Chemistry Letters p. 959 - 962 (1990)
Update date:2022-09-26
Topics:
Ozaki, Hiroaki
Nakamoto, Akio
Shimidzu, Takeo
Sequence-defined oligoribonucleosides having 2'-5' and/or 3'-5' phosphodiester linkage have been synthesized by use of 5'-protected ribonucleoside 2',3'-cyclic phosphoramidite on solid support.In coupling reaction, pKa of azole as a catalyst governs the activation.The resulting 2'-5' and/or 3'-5' linked oligoribonucleotides were easily separated by reversed-phase chromatography.
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