
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1725 - 1728 (1990)
Update date:2022-08-02
Topics:
Bekker, R. A.
Popkova, V. Ya.
A method has been found for the synthesis of fluoride-containing α-hydrothionyl fluorides by heating polyfluoroalkenyl benzyl sulfides having fluoride atoms in the α-position relative to the sulfur atom with fluorosulfonic acid.The reactions of the acid fluorides obtained with secondary amines were studied.The reaction of the α-hydrotetrafluorothiopropionyl fluoride with NH(Me)2 leads to the amide of the corresponding acid, while the product of α-hydrohexafluorothioisobutyryl fluoride with diethylamine is the dimer of bis(trifluoromethyl)thioketene.
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