Tetrahedron p. 3547 - 3558 (1990)
Update date:2022-07-29
Topics:
Jedlinski
Misioiek
Giowkowski
Janeczek
Wolinska
The potassium anions were found to react with ketones to39 yield both alcoholates and enolates. On the basis of the ESR and K NMR measurements the mechanism of this reaction is proposed. According to the proposed mechanism in the first step a ketyl radical is formed which after disproportionation yields an enolate and an alcoholate but only in the case of ketones having hydrogen atom in α-position in respect to carbonyl group.
View MoreContact:+86-0311-84455288-844
Address:Mayu Industrial Park, Jinzhou, Hebei, China.
Cangzhou Senary Chemical Science-tech Co., Ltd
Contact:+86-317-3563899, 3563699
Address:168 Jinde Road, Cangzhou, Hebei, China
Beijing Mashi Fine Chemical Co.,Ltd.
Contact:+86-10-61271592
Address:Room 506, Section B, Kaichi Mansion, Industrial Development
Contact:+86-913-2223392
Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
Beijing Mediking Biopharm Co., Ltd.
Contact:+86-10-89753524/81760121/81769521
Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
Doi:10.1007/s10593-011-0680-9
(2011)Doi:10.1002/zaac.19613070508
(1961)Doi:10.1007/s10593-011-0670-y
(2011)Doi:10.1039/c0ob00657b
(2011)Doi:10.1111/j.1747-0285.2011.01085.x
(2011)Doi:10.1002/anie.201102688
(2011)