N-(Silylmethyl)-Substituted Ketene N,S-Acetals as a Synthetic Equivalent of Novel 1,3-Dipolar Reagent, Alkylideneazomethine Ylids: Synthesis and Cycloadditions

DOI: 10.1021/jo00306a004

Source and publish data:

Journal of Organic Chemistry p. 5308 - 5310 (1990)

Update date:2022-08-05

Topics:

Authors:

Hosomi, Akira

Miyashiro, Yuji

Yoshida, Ryoji

Tominaga, Yoshinori

Yanagi, Toshiharu

Hojo, Makoto

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Article abstract of DOI:10.1021/jo00306a004

A variety of N-(silylmethyl)-substituted ketene N,S-acetals, readily prepared by the reaction of ketene dithioacetals with ((trimethylsilyl)methyl)amine, followed by N-alkylation, react smoothly with activated alkenes, carbonyl compounds, and thioketones,

Full text of DOI:10.1021/jo00306a004

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