Palladium Catalysis in Cephalosporin Chemistry: General Methodology for the Synthesis of Cephem Side Chains

DOI: 10.1021/jo00310a014

Source and publish data:

Journal of Organic Chemistry p. 5833 - 5847 (1990)

Update date:2022-09-26

Topics:

Authors:

Farina, Vittorio

Baker, Stephen R.

Benigni, Daniel A.

Hauck, Sheila I.

Sapino, Chester

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00310a014

We describe in full the palladium-catalyzed coupling of 3-(triflyloxy)cephems with organotin compounds, leading to the synthesis of 3-alkenyl-, 3-alkynyl-, and 3-arylcephems under exceptionally mild conditions.While this approach was not satisfactory for

Full text of DOI:10.1021/jo00310a014

Products guided by the article

Product name:(6R,7R)-7-tert-Butoxycarbonylamino-3-(1-methyl-1H-pyrrol-2-yl)-8-oxo-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester

Cas No:129849-13-4

R&D Labs maybe for 129849-13-4

Chongqing Yawei Fine Chemical Co.,Ltd

Contact:0086-23-62849407

Address:Ziyou village, Nanquan town, Banan district, Chongqing China
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
ANHUI WEICHI CHEMICAL CO.,LTD

website:http://www.weichichem.com

Contact:+8613912949432

Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Hangzhou Sartort Biopharma Co., Ltd

website:http://www.sartort.com

Contact:86-571-87039693

Address:No. 57, Tech Park Road, Hangzhou, Zhejiang, China
Evershine Chemical CO Ltd

Contact:+86-571-87010026

Address:202, Zhenhua Road,

Relevant to this article

Functionalization of Alkynes and Alkenes Using a Cascade Reaction Approach: Synthesis of β-Keto Sulfones under Metal-free Conditions

Doi:10.1021/acs.joc.9b02779
(2020)
Synthesis of simple CrL₄(alkyne) complexes by displacement of a labile cyclooctadiene ligand

Doi:10.1021/ja00179a054
(1990)
1,2-Functionalization of α,β-Epoxycycloalkanones

Doi:10.1021/jo00308a007
(1990)
Ring-opening fluorination of α, β-epoxy sulfoxides: A novel synthesis of α-fluoroketones

Doi:10.1248/cpb.38.1798
(1990)
Catalytic Regiodivergent Kinetic Resolution of Allylic Epoxides: A New Entry to Allylic and Homoallylic Alcohols with High Optical Purity

Doi:10.1021/jo035674h
(2004)
THERMAL ANALYSIS OF THE OXALATE HEXAHYDRATES AND DECAHYDRATES OF YTTRIUM AND THE LANTHANIDE ELEMENTS.

Doi:10.1016/0022-5088(80)90222-2
(1980)

Article Doi