Anti-Selective Reaction of α-Sulfenyl Acetals with Silylated Carbon Nucleophiles. Scope, Limitation, and Mechanism

DOI: 10.1021/jo00055a009

Source and publish data:

Journal of Organic Chemistry p. 579 - 587 (1993)

Update date:2022-08-03

Topics:

Authors:

Kudo, Kazuaki

Hashimoto, Yukihiko

Sukegawa, Makoto

Hasegawa, Masaki

Saigo, Kazuhiko

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Article abstract of DOI:10.1021/jo00055a009

In the presence of a Lewis acid, α-sulfenyl acetals 1 reacted with various silylated carbon nucleophiles 2 to give anti adducts (anti-3) with high diastereoselectivity.The stereochemistry was only slightly affected by the reaction conditions, such as temp

Full text of DOI:10.1021/jo00055a009

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