O-Alkylation at the anomeric centre for the stereoselective synthesis of Kdo-α-glycosides

DOI: 10.1016/0008-6215(90)84198-4

Source and publish data:

Carbohydrate Research p. 287 - 305 (1990)

Update date:2022-08-05

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Authors:

Esswein, Angelika

Rembold, Hansjoerg

Schmidt, Richard R.

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Article abstract of DOI:10.1016/0008-6215(90)84198-4

O-Alkylation at the anomeric centre of the dianion of 4,5:7,8-di-O-cyclohexylidene-3-deoxy-N-methyl-α-D-manno-octulopyranosonamide (1) with several triflates led diastereoselectively to the α-glycosides.In this way, lipopolysaccharide building-blocks cont

Full text of DOI:10.1016/0008-6215(90)84198-4

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