Synthetic Studies on Quassinoids: Total Synthesis of (+/-)-Shinjulactone C

DOI: 10.1021/jo00310a009

Source and publish data:

Journal of Organic Chemistry p. 5816 - 5818 (1990)

Update date:2022-07-29

Topics:

Authors:

Collins, Jon L.

Grieco, Paul A.

Gross, Raymond S.

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Article abstract of DOI:10.1021/jo00310a009

The total synthesis of the novel quassinoid Shinjulactone C (1) is detailed which proceeds via pentacyclic lactone 3 and features new protocols for elaboration of the ring A 1β-hydroxy-2-oxo-Δ^3,4 olefin unit and the C(8),C(11) bridged hemiketal array which are present in 3 and common to numerous quassinoids.

Full text of DOI:10.1021/jo00310a009

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