Synthetic Studies on Quassinoids: Total Synthesis of (+/-)-Shinjulactone C

DOI: 10.1021/jo00310a009

Source and publish data:

Journal of Organic Chemistry p. 5816 - 5818 (1990)

Update date:2022-07-29

Topics:

Authors:

Collins, Jon L.

Grieco, Paul A.

Gross, Raymond S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00310a009

The total synthesis of the novel quassinoid Shinjulactone C (1) is detailed which proceeds via pentacyclic lactone 3 and features new protocols for elaboration of the ring A 1β-hydroxy-2-oxo-Δ^3,4 olefin unit and the C(8),C(11) bridged hemiketal array which are present in 3 and common to numerous quassinoids.

Full text of DOI:10.1021/jo00310a009

Products guided by the article

Product name:(3S,3aS,5S,6aR,7aS,8R,11aS,11bS,11cS)-11c-(tert-Butyl-diphenyl-silanyloxymethyl)-5-methoxy-3,8,11a-trimethyl-3a,4,5,6a,7,7a,8,9,10,11a,11b,11c-dodecahydro-3H-6-oxa-benzo[de]anthracen-11-one

Cas No:130146-60-0

R&D Labs maybe for 130146-60-0

Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Rizhao Lanxing Chemical Indusrial Co.,Ltd

Contact:86-633-2616708

Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
Henan Harvest Chem Co., Ltd

Contact:+86-371-86058576

Address:NO.32, Jingsan Road, Zhengzhou, China

Relevant to this article

Precursor Catenand Complexes: Synthesis, Structure, and Electrochemistry of Bis(2,6-di-iminopyridyl) Complexes of Nickel(II). The Single-crystal X-Ray Structure of 42>2

Doi:10.1039/DT9890000965
(1989)
Stereoselective synthesis of 2-thioglycosides of N-acetylneuraminic acid

Doi:10.1016/0008-6215(89)80054-0
(1989)
The magic of small structure differences in a sodium-glucose cotransporter drug discovery project—¹⁴C-labelled drug candidates in a key-differentiating study

Doi:10.1002/jlcr.3869
(2021)
Cationic organomagnesium complexes as highly active initiators for the ring-opening polymerization of ε-caprolactone

Doi:10.1021/om900669y
(2010)
Conversion of (3 S,4 R)-tetrahydrodaidzein to (3 S)-equol by THD reductase: Proposed mechanism involving a radical intermediate

Doi:10.1021/bi100465y
(2010)
Complications in the Reactions of Tris(thio)methyl-lithium Derivatives with δ-Valerolactone

Doi:10.1039/c39890000177
(1989)

Article Doi