Tetrahedron Letters p. 2901 - 2904 (1990)
Update date:2022-08-04
Topics:
Kim, Sunggak
Kim, Youn Chul
It was found that 1-alkoxyallylphosphonium salts underwent allylic 1,3-rearrangement to afford 3-alkoxyallylphosphonium salts.Reaction of 1-alkoxy-2-alkenylene-phosphoranes with aldehydes gave α-adducts, whereas the reaction in the presence of TMSOTf gave γ-adducts.
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