Tetrahedron Letters p. 3237 - 3240 (1990)
Update date:2022-08-04
Topics:
Koenig, Thomas M.
Daeuble, John F.
Brestensky, Donna M.
Stryker, Jeffrey M.
In contrast to organocuprate conjugate addition and standard methods for conjugate reduction, use of the stable copper(I) hydride cluster, <(Ph3P)CuH>6, allows chemoselective conjugate reduction of α,β-unsaturated carbonyl compounds substituted at the γ-position with leaving groups.In addition, the compatibility of the conjugate reduction with organic halides and sulfonate groups is demonstrated.
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Doi:10.1016/S0040-4039(01)87488-8
(1971)Doi:10.1021/ja202103e
(2011)Doi:10.1021/jo00004a012
(1991)Doi:10.1055/s-1990-27019
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(2011)Doi:10.1016/S0040-4020(01)87847-9
(1990)
