Tetrahedron Letters p. 3237 - 3240 (1990)
Update date:2022-08-04
Topics:
Koenig, Thomas M.
Daeuble, John F.
Brestensky, Donna M.
Stryker, Jeffrey M.
In contrast to organocuprate conjugate addition and standard methods for conjugate reduction, use of the stable copper(I) hydride cluster, <(Ph3P)CuH>6, allows chemoselective conjugate reduction of α,β-unsaturated carbonyl compounds substituted at the γ-position with leaving groups.In addition, the compatibility of the conjugate reduction with organic halides and sulfonate groups is demonstrated.
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