A Convenient Method for the Synthesis of Substituted 2-Methoxycarbonyl- and 2-Cyanoallylphosphonates. The Allyl Phosphite - Allylphosphonate Rearrangement

DOI: 10.1055/s-1990-27019

Source and publish data:

Synthesis p. 799 - 801 (1990)

Update date:2022-08-04

Topics:

Authors:

Janecki, Tomasz

Bodalski, Ryszard

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Article abstract of DOI:10.1055/s-1990-27019

The thermally induced Arbuzov rearrangement of allyl diethyl phosphites gives, under unprecedented mild conditions, a variety of diethyl allylphosphonates with high stereoselectivity and in high yield.

Full text of DOI:10.1055/s-1990-27019

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