Tetrahedron Letters p. 6135 - 6138 (1989)
Update date:2022-08-03
Topics:
Yon-Hin
Wijesekera
Dolphin
A β-unsubstituted-β'-vinylporphyrin has been synthesized which reacted with an excess of acetylenedicarboxylate ester to give monobenzoporphyrins in high yield. Evidence that suggests an isomerization of the initial adduct to a new porphyrin enroute to the benzoporphyrin is presented.
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