10.1002/ejoc.201900144
European Journal of Organic Chemistry
FULL PAPER
Hz), 146.8 (d, JC-P = 3.3 Hz), 135.2 (d, JC-P = 17.6 Hz), 131.2 (d, JC-P
10.1 Hz), 129.8, 129.7 (d, JC-P = 107.6 Hz), 128.7, 127.7, 125.5 (d, JC-P
=
=
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12.2 Hz), 119.9 (d, JC-P = 103.7 Hz), 34.9, 31.1. 31P NMR (162 MHz,
CDCl3): δ 24.17. HRMS(ESI) calc. for C28H34OP (M+H)+: 417.2342, found
417.2340.
(E)-bis(3,5-dimethylphenyl)(styryl)phosphine oxide (3x): Yellow solid,
m.p. 158-159 oC. 1H NMR (400 MHz, CDCl3): δ 7.89 (s, 1H), 7.55-7.46
(m, 3H), 7.38-7.35 (m, 7H), 7.15 (s, 2H), 6.83 (dd, J1 = 17.5 Hz, J2 = 22.5
Hz, 1H), 2.34 (s, 12H). 13C NMR (100 MHz, CDCl3): δ 146.9 (d, JC-P = 3.4
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Hz), 138.2 (d, JC-P = 12.7 Hz), 135.2 (d, JC-P = 17.4 Hz), 133.5 (d, JC-P
=
2.7 Hz), 132.7 (d, JC-P = 104.5 Hz), 129.9, 128.8, 128.7, 127.7, 119.5 (d,
JC-P = 103.0 Hz), 21.2. 31P NMR (162 MHz, CDCl3): δ 24.95. HRMS(ESI)
calc. for C24H26OP (M+H) +: 361.1716, found 361.1710.
Acknowledgments
We thank the Natural Science Foundation of Shandong Province
(no. ZR2017LB007 and ZR2017BEM016),
Shandong Province Higher Educational Science and
Technology Program (no. J18KA074) and Project of
A
Project of
A
Shandong Province Joint Postgraduate-Education Training Base
Construction (no. 07195) for financial support.
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4230.
Keywords: phosphorylation • dehydrogenation •
alkenylphosphine oxides • spontaneous elimination • radicals
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