CHIRAL AMINAL TEMPLATES 3. DIASTEREOSELECTIVITY OF ORGANOMETALLIC ATTACK ON ALDEHYDES BEARING A CHIRAL IMIDAZOLIDINE GROUP

DOI: 10.1016/S0957-4166(00)86314-4

Source and publish data:

Tetrahedron Asymmetry p. 283 - 286 (1990)

Update date:2022-08-05

Topics:

Authors:

Alexakis, A.

Sedrani, R.

Normant, J. F.

Mangeney, P.

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Article abstract of DOI:10.1016/S0957-4166(00)86314-4

Monoprotected phthalaldehydes 3 and 4, bearing a chiral imidazolidine auxiliary were reacted with various organometallic reagents.Lithium organocuprates gave almost exclusively one diastereomer whereas an organomanganese reagent gave the opposite one.Hydr

Full text of DOI:10.1016/S0957-4166(00)86314-4

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