TRIFLUOROMETHYL AND MIXED HYDRIDO TRIFLUOROMETHYL COMPLEXES OF IRIDIUM(III) AS POTENTIAL PRECURSORS OF AN IRIDIUM(I) TRIFLUOROMETHYL COMPLEX

DOI: 10.1016/0022-328X(86)82021-6

Source and publish data:

Journal of Organometallic Chemistry p. 245 - 250 (1986)

Update date:2022-09-26

Topics: Characterization applications

Authors:

Greene, T. R.

Roper, W. R.

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Article abstract of DOI:10.1016/0022-328X(86)82021-6

Abstraction of iodide from Ir(CF3)ClI(CO)(PPh3)2 (1) by AgSbF6 in the presence of acetonitrile yields the cationic complex ⁺^- (2).The acetonitrile group of 2 is readily displaced, and 2 reacts with p

Full text of DOI:10.1016/0022-328X(86)82021-6

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Product name:Ir(CF₃)HCl(CO)[P(C₆H₅)3]2

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