The Synthesis of 1H-, 3H-, and 5H-2-Benzazepine Derivatives in the Reaction of Bicyclic Aromatic Nitro Compounds with Dimethyl Phosphite and Amines in the Basic Conditions

Article abstract of DOI:10.1021/jo00003a063

1- and 2-nitronaphthalenes and 5-, 6-, and 8-nitroquinolines react with dimethyl phosphite and various primary and secondary amines in the presence of NaOMe in MeOH to give 1H-, 3H, and 5H-2-benzazepine or pyridazepine derivatives.Some structural features