REDUCTIVE AND OXIDATIVE REACTIONS OF CALIXARENE DERIVATIVES

DOI: 10.1016/S0040-4039(00)85995-X

Source and publish data:

Tetrahedron Letters p. 1909 - 1912 (1991)

Update date:2022-07-29

Topics:

Authors:

Grynszpan, Flavio

Dinoor, Nahum

Biali, Silvio E.

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Article abstract of DOI:10.1016/S0040-4039(00)85995-X

Reductive cleavage of 25,26,27,28-tetramethoxy-p-tert-butylcalix<4>arene with K results in the formation of 26,28-dimethoxy-p-t-butylcalix<4>arene.The reaction of 25,27-dihyroxycalix<4>arene with NO2BF4 in acetonitrile results in its oxidation to calixdiquinone 6.

Full text of DOI:10.1016/S0040-4039(00)85995-X

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