Iodonium ion promoted reactions at the anomeric centre. II: An efficient thioglycoside mediated approach toward the formation of 1,2-trans linked glycosides and glycosidic esters

Article abstract of DOI:10.1016/S0040-4039(00)88799-7

N-iodosuccinimide (NIS) in the presence of an organic acid was found to be effective for the activation of fully acylated thioglycosides leading to 1,2-trans linked esters. On the other hand, NIS together with a catalytic amount of trifluoromethanesulfoni