Construction of Trifluoromethylated Quarternary Carbons via Diels-Alder Reactions of 2-(Trifluoromethyl)propenoic Acid Derivatives: Application to the Synthesis of 16,16,16-Trifluororetinal

DOI: 10.1021/jo00005a014

Source and publish data:

Journal of Organic Chemistry p. 1718 - 1725 (1991)

Update date:2022-08-02

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Authors:

Hanzawa, Yuji

Suzuki, Makoto

Kobayashi, Yoshiro

Taguchi, Takeo

Iitaka, Yoichi

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Article abstract of DOI:10.1021/jo00005a014

Diels-Alder reactions of 2-(trifluoromethyl)propenoic acid (1) and its 2,2,2-trifluoroethyl ester 2 with various dienes gave adducts in good yields.In Lewis acid catalyzed Diels-Alder reactions of 2, the combination of the Lewis acid and solvent proved to

Full text of DOI:10.1021/jo00005a014

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