Evidence for "stable" organocopper intermediates in the reaction between Me2CuLi·Lil and allylic sulfinyl mesylates

DOI: 10.1016/S0040-4039(00)61252-2

Source and publish data:

Tetrahedron Letters p. 4985 - 4988 (1992)

Update date:2022-07-29

Topics:

Authors:

De La Pradilla, Roberto Fernandez

Rubio, M. Belen

Marino, Joseph P.

Viso, Alma

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Article abstract of DOI:10.1016/S0040-4039(00)61252-2

The addition of Me₂CuLi·LiI to acyclic allylic sulfinyl mesylates bearing a phenyl functionality in the molecule gives rise to chiral allenes 4 and 11 in variable yields and optical purities, presumably via an unusually stable σ-copper(III) spe

Full text of DOI:10.1016/S0040-4039(00)61252-2

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