A Highly Efficient Synthesis of Tri-O-Acyl-α-D-Glucopyranose 1,2-(Orthoesters) under High Pressure

DOI: 10.1246/cl.1990.2099

Source and publish data:

Chemistry Letters p. 2099 - 2102 (1990)

Update date:2022-08-02

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Authors:

Gama, Yasuo

Sasaki, Makoto

Yasumoto, Masahiko

Ishigami, Yutaka

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Article abstract of DOI:10.1246/cl.1990.2099

High pressure-assisted condensation reaction of acylated glucosyl bromides with complex alcohols in the presence of diisopropylethylamine and tetrabutylammonium bromide gave the corresponding 1,2-orthoesters in good to excellent yields without using heavy

Full text of DOI:10.1246/cl.1990.2099

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