Sequential Radical Cyclization/Intermolecular Carbonyl Addition Reactions Initiated by Samarium(II) Iodide

DOI: 10.1021/jo00004a020

Source and publish data:

Journal of Organic Chemistry p. 1439 - 1445 (1991)

Update date:2022-08-05

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Authors:

Molander, Gary A.

Kenny, Caryn

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Article abstract of DOI:10.1021/jo00004a020

A sequential reductive coupling process promoted by samarium(II) iodide (SmI2) is described.Thus, ethyl 2-acetyl-2-methyl-5-hexenoate, upon treatment with SmI2 in the presence of a variety of aldehydes or ketones, undergoes an initial radical (ketyl) olef

Full text of DOI:10.1021/jo00004a020

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