Anodic Oxidation of Triphenylphosphine in the Presence of Enol Silyl Ethers or Enol Esters. Electrochemical One-step Preparation of 2-Oxocycloalkyltriphenylphosphonium Tetrafluoroborates

DOI: 10.1039/c39900001310

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1310 - 1311 (1990)

Update date:2022-09-26

Topics:

Authors:

Takanami, Toshikatsu

Abe, Akie

Suda, Kohji

Ohmori, Hidenobu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900001310

Electrochemical oxidation of triphenylphosphine in the presence of cyclic enol silyl ethers or enol esters gave 2-oxocycloalkyltriphenylphosphonium salts, which underwent the Wittig reaction with aldehydes to afford (E)-2-alkylidenecycloalkan-1-ones.

Full text of DOI:10.1039/c39900001310

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-Methyl-6-[3-phenyl-prop-(E)-ylidene]-cyclohexanone

Cas No:132228-63-8

R&D Labs maybe for 132228-63-8

Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo
Taizhou Huading Chemical Co.,Ltd(expird)

Contact:+86-576-88583898

Address:Economic&Technology development zone,Taizhou City,Zhejiang Province,China
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Accela ChemBio Inc.

Contact:1-858-6993322

Address:9883 Pacific Heights Blvd., Suite H, San Diego

Relevant to this article

Donor-acceptor-donor-based π-conjugated oligomers for nonlinear optics and near-IR emission

Doi:10.1021/cm201424a
(2011)
DIRECT DETECTION OF TWO METAPHOSPHORAMIDATES IN -75 DEG C THF SOLUTIONS BY 31P NMR SPECTROSCOPY

Doi:10.1016/S0040-4039(00)97094-1
(1990)
Synthesis and dopamine receptor affinities of 1-aminoethylhetero-tetralines

Doi:10.1016/0223-5234(91)90129-B
(1991)
An unusual oxidative cyclization. A synthesis and absolute stereochemical assignment of (-)-rocoglamide

Doi:10.1021/ja00180a081
(1990)
An Atom-Economical Method for the Formation of Amidopyrroles Exploiting the Self-Assembled Resorcinarene Capsule

Doi:10.1021/acs.orglett.0c00529
(2020)
STEREOSELECTIVITIES IN THE COUPLING REACTION BETWEEN SILYLATED PYRIMIDINE BASES AND 1-HALO-2,3-DIDEOXYRIBOSE

Doi:10.3987/COM-90-5563
(1990)

Article Doi