Facile Synthesis of the Matallacyclic Rings , and ; Crystal Structures of and

DOI: 10.1039/c39900001535

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1535 - 1537 (1990)

Update date:2022-07-30

Topics:

Authors:

Kemmitt, Raymond D. W.

Mason, Simon

Moore, Mark R.

Fawcett, John

Russell, David R.

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Article abstract of DOI:10.1039/c39900001535

Reaction of PhCOCH2P(O)(Ph)CH2COPh, RNHP(O)(Ph)NHR or RNHS(O)2NHR (R = H or Ph) with cis- (L = PPh3 or PMePh2; L2 = Ph2PCH2CH2PPh2 or cycloocta-1,5-diene) in the presence of silver(I) oxide gives metallacyclic complexes of the type , or respectively; single crystal X-ray studies on and the insertion product establish the presence of puckered metallacycles, the oxygen of the platinaphosphetane-3-oxide adopting an equatorial environment.

Full text of DOI:10.1039/c39900001535

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