Journal of Organic Chemistry p. 1700 - 1707 (1991)
Update date:2022-07-30
Topics:
Duddeck, Helmut
Rosenbaum, Doris
The synthesis of a number of substituted 2-tert-butyladamantan-2-ols from the corresponding ketones is described.In addition to these addition reactions, some unexpected rearrangements were observed.Reaction mechanisms are proposed to rationalize the experimental results. 13C NMR spectra of some adamantanes are discussed in terms of substituent interaction effects.
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