Reaction of ketene silyl acetals with unsaturated nitrites in the presence of titanium tetrachloride

DOI: 10.1016/S0040-4020(01)87886-8

Source and publish data:

Tetrahedron p. 7011 - 7018 (1990)

Update date:2022-08-04

Topics:

Authors:

Ali, Syed Masarrat

Rousseau, Gerard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)87886-8

The reaction of ketene alkyl silyl acetals with acrylonitrile in the presence of titanium tetrachloride in dichloromethane at -80°C leads to coupled compounds. Formation of these products can be explained by the transformation of ketene acetals into enoxy

Full text of DOI:10.1016/S0040-4020(01)87886-8

Products guided by the article

Product name:dimethyl 4,5-dicyano-2,2,7,7-tetramethyloctanedioate

Cas No:132282-18-9

R&D Labs maybe for 132282-18-9

Tianjin Pharmacn Medical Technology Co.,Ltd.

Contact:86-22-60122566ext.866(English),23359620

Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
Chengdu Push Bio-technology Co., Ltd

Contact:--

Address:No.8 Wuke West Second Road, Wuhou
Neworld Chemical Co., Ltd Shanghai(expird)

Contact:+86-21-62202658

Address:11F, Blvd 2, No. 1969 PuXing Rd, Shanghai
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
wuxi huabin bio-tech Co.,Ltd(expird)

Contact:86-0510-85133006

Address:hubin road NO157

Relevant to this article

Solution-phase total synthesis of the hydrophilic natural product argifin using 3,4,5-tris(octadecyloxy)benzyl tag

Doi:10.1016/j.tet.2011.05.073
(2011)
PXD101 analogs with L-phenylglycine-containing branched cap as histone deacetylase inhibitors

Doi:10.1111/cbdd.12787
(2016)
Colistin sulfate chiral stationary phase for the enantioselective separation of pharmaceuticals using organic polymer monolithic capillary chromatography ^?

Doi:10.3390/molecules24050833
(2019)
Benzyl and sulfonyl derivatives of n-(2,6-dimethylphenyl)-2(piperazin-1-yl)acetamide (t2288): biological screening and fingerprint applications

Doi:10.13005/ojc/350117
(2019)
An efficient one pot synthesis of bicyclic dienones

Doi:10.1039/a902012h
(1999)
Towards a KCC2 blocker pharmacophore model

Doi:10.1016/j.bmcl.2012.04.097
(2012)

Article Doi