Journal of Organometallic Chemistry p. 247 - 258 (1993)
Update date:2022-07-29
Topics:
Clark, T. Jeffrey
Killian, Christopher M.
Luthra, Sanjay
Nile, Terence A.
The synthesis of 1,3-dialkyl substituted cyclopentadienes, C5H4RR', Cp'H (Va-g) (where R and R' are tert-butyl, iso-propyl, neo-pentyl, cyclohexyl, or 1-methylcyclohexyl) is reported.These are synthesized by the nucleophilic addition of methyl or hydride anions to the corresponding 2-alkyl-6,6-dialkylfulvenes (IIIa-f) followed by hydrolysis.These substituted 1,3-cyclopentadienes have been converted to organometallic derivatives such as
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