Radical Substitution on the Sulphur of Thioester Group

DOI: 10.1039/c39900001408

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1408 - 1409 (1990)

Update date:2022-09-26

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Authors:

Tada, Masaru

Uetake, Tomohiro

Matsumoto, Mitsuhiro

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Article abstract of DOI:10.1039/c39900001408

Intermolecular reaction of an organo-radical with thioester gives the sulphide, which is formed by the sulphur centred substitution of acyl groups with a nucleophilic organo-radical, but no displacement of S-alkyl groups with the organo-radical takes place.

Full text of DOI:10.1039/c39900001408

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