Metal-assisted reactions. Part 20. Catalytic transfer hydrogenolysis of phenolic C-O bonds

DOI: 10.1016/S0040-4039(00)97960-7

Source and publish data:

Tetrahedron Letters p. 5789 - 5790 (1990)

Update date:2022-08-05

Topics:

Authors:

Brigas Brigas

Johnstone

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Article abstract of DOI:10.1016/S0040-4039(00)97960-7

After conversion of phenols into O-pseudosaccharyl ethers (2) catalytic transfer hydrogenolysis with Pd/C catalyst and sodium phosphinate as hydrogen donor gave arenes (ArH) in good yield. As an example of the application of this reaction in synthesis, oestrone was onverted into oestratrienone in a high yielding, one step reaction.

Full text of DOI:10.1016/S0040-4039(00)97960-7

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