
Tetrahedron Letters p. 5789 - 5790 (1990)
Update date:2022-08-05
Topics:
Brigas
Johnstone
After conversion of phenols into O-pseudosaccharyl ethers (2) catalytic transfer hydrogenolysis with Pd/C catalyst and sodium phosphinate as hydrogen donor gave arenes (ArH) in good yield. As an example of the application of this reaction in synthesis, oestrone was onverted into oestratrienone in a high yielding, one step reaction.
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(2010)Doi:10.1021/ol101336y
(2010)