Selectivity in the propargylation of polyfunctional amines by (propargylium)-Co2(CO)6+ and -(C5H5)2Mo2(CO)4+

DOI: 10.1016/0022-328X(90)85496-L

Source and publish data:

Journal of Organometallic Chemistry p. 317 - 326 (1990)

Update date:2022-07-29

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Authors:

Gruselle, M.

Philomin, V.

Chaminant, F.

Jaouen, G.

Nicholas, K. M.

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Article abstract of DOI:10.1016/0022-328X(90)85496-L

<(HC<*>CCH2)Co2(CO)6>BF4 (1) and <(HC<*>CCH2)Mo2(C5H5)2(CO)4>BF4 (2) react with primary and secondary amines in CH2Cl2 solution.In the case of primary amines, the products of mono and dialkylation are obtained.The more stable (less reactive) molybdenum co

Full text of DOI:10.1016/0022-328X(90)85496-L

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Product name:{(HCCo₂(CO)6CCH₂)(H)N(COCH₃)CH₂CH₂C₆H₂(OCH₃)2}

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